Electrochemical reduction of 2,4-dinitrophenol on nanocomposite electrodes modified with mesoporous silica and poly(vitamin B1) films

Electrochemical reduction of 2,4-dinitrophenol was investigated on a glassy carbon electrode modified with a nanocomposite Santa Barbara Amorphous silica (SBA-15) film and poly(vitamin B-1) film. For sensitive and selective detections, vanadium pentoxide and cerium oxide nanoparticles were incorporated into the matrix of SBA-15. 2,4-Dinitrophenol was reduced on the modified electrode at -0.39 and -0.25V, corresponding to the reduction of 4-dinitrophenol and 2-dinitrophenol, respectively. Both cathodic peak currents were controlled by the diffusion of 2,4-dinitrophenol. The amplitude of the peak currents was proportional to the 2,4-dinitrophenol concentration in the range of 3.0-30 mu M. The modified electrode demonstrated a long lifetime for the detection of 2,4-dinitrophenol. The detection limit of 2,4-dinitrophenol was 0.5 mu M. Moreover, the modified electrode was used successfully to detect 2,4-dinitrophenol in lake water. (C) 2011 Elsevier Ltd. All rights reserved.