期刊
ELECTROCHIMICA ACTA
卷 55, 期 15, 页码 4506-4511出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2010.02.094
关键词
Oxygen reduction reaction; Electrocatalyst; Pd; Carbon-supported silver; Alkaline media
资金
- U.S. Army Research Lab [W911NF-07-2-0036]
We synthesized and characterized a highly active electrocatalyst for oxygen reduction reactions (ORRs) in alkaline media by coating carbon-supported silver nanoparticles with Pd (Pd@Ag/C) via a galvanic displacement method. The electrochemical measurements were carried out using an ultrathin film rotating disk electrode Compared to the Pt/C electrocatalyst, the specific and mass activities of the Pd@Ag/C were enhanced by a factor of 3 and 25. respectively. The potentiostatic measurements showed that the Pd@Ag/C is less stable than the Pt/C at the potential of -0 1 V vs. Hg/HgO/OH- in alkaline media The Pd@Ag/C is insensitive to alcohol, and, as a cathode electrocatalyst of a direct alcohol fuel cell, can resist poisoning by the possible alcohol crossover from the anode. (C) 2010 Elsevier Ltd. All rights reserved.
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