期刊
ELECTROCHIMICA ACTA
卷 55, 期 15, 页码 4495-4500出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2010.02.092
关键词
Electrosynthesis; Arylpyridazines; Catalyzed; Nickel-2,2 '-bipyridine complexes; Cyclic voltammetry
资金
- Universite Paris Est Creteil Val de Marne (UPEC)
- ANR
The nickel-2,2'-bipyridine catalyzed electrochemical cross-coupling reaction between an aryl halide and a chloropyridazine was investigated by an electrochemical study The electrochemical behavior of the divalent nickel complex is affected by the presence of pyridazine rings which act as co-ligands of nickel Cyclic voltammetry indicates that the cross-coupling reaction involves first a rapid oxidative addition of the chloropyridazine on the electrogenerated zerovalent nickel complex. The coupling product is then obtained by reaction with the aryl halide. (C) 2010 Elsevier Ltd. All rights reserved.
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