4.6 Article

Synthesis of tellurium nanotubes by galvanic displacement

期刊

ELECTROCHIMICA ACTA
卷 55, 期 7, 页码 2472-2476

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2009.12.002

关键词

Tellurium; Nanotube; Galvanic displacement; Thermoelectrics; Magnetoresistance

资金

  1. Korean Ministry Science and Technology (MOST) [K207010000284-07A0100]

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Tellurium nanotubes with controlled diameter and wall thickness were synthesized by galvanic displacement of cobalt nanowires and their temperature dependent field effect transistor and magnetoresistance properties were systematically investigated. The nanotube diameter was slightly larger than the sacrificial cobalt nanowire diameter with a wall thickness of range from 15 to 30 nm depending on the diameter of cobalt nanowires. Te nanotubes show p-type semiconducting property with the field effect carrier mobility of approx. 0.01 cm(2)/V s which is relatively lower than other 1D nanostructure. Low mobility might be attributed to porous morphology with small grain size (<10 nm). Temperature dependent mobility also exhibiting a Conwell-Weisskopf relationship, to temperatures below 250 K, indicating that the dominant scattering sites are ionized impurity centers. Unique MR behavior was observed from nanotube with a maximum magneto resistance ratio of 37% at 260 K. (C) 2009 Elsevier Ltd. All rights reserved.

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