Current efficiency studies for graphite and SnO2-based anodes for the electro-deoxidation of metal oxides

Studies were performed investigating the electrochemical reduction of chromium oxide (Cr2O3) by electro-deoxidation by utilising either a graphite anode or a tin oxide (SnO2) based anode. Potentiostatic electrolysis was performed at 3.0 V for both a graphite and for a SnO2-based anode, and also 2.0 V for a graphite anode. The cathode reduction purity, anode mass change, anode potential relative to a glassy carbon pseudo-reference and current efficiency were measured and compared. The key observations are that substituting a SnO2-based anode for a graphite anode led to greater current efficiencies for electro-deoxidation. This was attributed to the lack of contamination of the melt by carbon and the lower cathode potential due to the higher anodic potential when using tin oxide based anodes for the same applied voltage. The current efficiency was also found to decrease with both anode materials when higher anode surface areas or lower current densities were used. Again this was attributed to a decrease in anodic potentials and a corresponding increase in the cathodic potential resulting in a greater number of parasitic reactions occurring at the cathode. (C) 2010 Elsevier Ltd. All rights reserved.