期刊
ELECTROCHIMICA ACTA
卷 55, 期 20, 页码 5624-5628出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2010.04.094
关键词
Porous carbon; Novolac resin; Nitrogen atom; Porosity; X-ray photoemission spectroscopy; Capacitance
资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan [19002007]
We fabricated nitrogen-decorated porous carbon exhibiting high capacitance per unit volume and unit weight via chemical activation of novolac resin containing peptide linkage. The porosity and the amount of nitrogen atoms were controlled by changing the molecular weight of novolac resin, the added amount of potassium hydroxide, or both. After chemical activation, positively charged nitrogen atoms (i.e., pyridine/pyrrole) at 400.3 eV in photoemission spectra contributed to both a shift in the point of zero charge toward negative potential and the generation of pseudocapacitance. Suitably developed pores and the positively charged nitrogen atoms make nitrogen-decorated novolac resin-derived porous carbon a promising material for electrodes in high-performance supercapacitors. (C) 2010 Elsevier Ltd. All rights reserved.
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