期刊
ELECTROCHIMICA ACTA
卷 54, 期 28, 页码 7227-7230出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2009.07.028
关键词
Electrostatic Spray Deposition (ESD); SnO2; Anode; Li-ion battery; Porous structure
资金
- AFOSR [FA9550-08-1-0287l]
- National Science Foundation of China [50372064]
Three-dimensional (3D) porous amorphous SnO2 thin films were deposited on Ni foam substrates by Electrostatic Spray Deposition (ESD) technique as anodes for Li-ion batteries. These films display good capacity retention of 94.8% after 100 cycles at 0.5 C and rate capability of 362 mAh/g at 10C. The improved performance originates from the fact that the 3D porous structure offers a buffer zone to accommodate the large volume change during cycling. and the foam-like substrate maximizes the contact area between electrode and electrolyte. The facile ESD method can be potentially extended to prepare other 3D porous functional materials. Published by Elsevier Ltd.
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