A mechano- and electrochemically controlled SnSb/C nanocomposite for rechargeable Li-ion batteries

At present, graphite (LiC6: 372 mAh g(-1), 840 mAh cm(-3)) is used as the anode material for lithium-ion batteries. However, methods to enhance the energy density, cyclability, initial Coulombic efficiency, and rate capability of lithium-ion batteries are still actively being researched. Here, we report a simple. fast, and novel method for transforming micron-sized Sn and Sb powders into ca. 10 nm- and 2-3 nm-sized SnSb crystallites by mechanochemical synthesis and electrochemical reactions, respectively. These nanocrystallites are uniformly distributed in an amorphous carbon matrix, resulting in a SnSb/C nanocomposite structure. The fabricated SnSb/C nanocomposite showed excellent electrochemical properties, such as a high energy density (1 st charge: 706 mAh g(-1)), long cyclability (ca. 550 mAh g-1 over 300 cycles), good initial Coulombic efficiency (ca. 81%). and a fast rate capability (1C: 590 mAh g(-1), 2C: 550 mAh g(-1)). (c) 2009 Elsevier Ltd. All rights reserved.