期刊
ELECTROCHIMICA ACTA
卷 54, 期 21, 页码 4910-4915出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2009.04.004
关键词
Multi-wall carbon nanotubes; Vanillin; Carbon fiber electrode; Rotating disk electrode; Nitrite
资金
- National Nature Science Foundation of China [30770549, 20805035, 90817103]
We report a simple method for the stable dispersion of multi-walled carbon nanotubes (MWNTs) in water by vanillin and controllable surface addition onto carbon fiber microelectrodes (CFE) via electropolymerization. We have characterized these polyvanillin-carbon nanotube (PVN-MWNT) composite films with techniques including scanning electron microscopy (SEM), infrared spectroscopy (IR) and voltammetry. These investigations showed that the films have a uniform porous nanostructure with a large surface area. This PVN-MWNT composite-modified CFE (PVN-MWNT/CFE) exhibited a sensitive response to the electrochemical oxidation of nitrite. Under optimal working conditions, the oxidation peak current of nitrite linearly increased with its concentration in the range of 0.2 mu M-3.1 mM, with the system exhibiting a lower detection limit of 50 nM (S/N = 3). We successfully applied the PVN-MWNT/CFE system to the determination of nitrite from lake water. The efficient recovery of nitrite indicated that this electrode was able to detect nitrite in real samples. (C) 2009 Elsevier Ltd. All rights reserved.
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