期刊
ELECTROCHIMICA ACTA
卷 54, 期 21, 页码 4872-4879出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2009.03.092
关键词
Cyanomethylation; Arylation; Dimethylaminocarbonylation; Radical coupling; 1,4-Dioxins
资金
- Spanish Ministry of Science and Education [CTQ2007-62612/BQU]
The electrochemical reduction of a series of quinones in DMF, acetonitrile and 1,2-dichloroethane under controlled potential conditions and in the presence/absence of benzene diazonium tetrafluoroborate. is presented. It provides an interesting entry to new hydroxycarboxamides, dioxins, cyanomethylated derivatives, and other useful compounds. The electrochemical behaviour of these systems and mechanistic proposals are given. (C) 2009 Elsevier Ltd. All rights reserved.
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