期刊
ELECTROCHIMICA ACTA
卷 53, 期 22, 页码 6610-6615出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2008.04.054
关键词
gold nanoparticles self-assembled electrode; uric acid; ascorbic acid; simultaneous determination; differential pulse voltammetry
A new gold nanoparticles-modified electrode (GNP/LC/GCE) was fabricated by self-assembling gold nanoparticles to the surface of the L-cysteine-modified glassy carbon electrode. The modified electrode showed an excellent character for electrocatalytic oxidization of uric acid (UA) and ascorbic acid (AA) with a 0.306 V separation of both peaks, while the bare GC electrode only gave an overlapped and broad oxidation peak. The anodic currents of UA and AA on the modified electrode were 6- and 2.5-fold to that of the bare GCE, respectively. Using differential pulse voltammetry (DPV), a highly selective and simultaneous determination of UA and AA has been explored at the modified electrode. DPV peak currents of UA and AA increased linearly with their concentration at the range of 6.0 x 10(-7) to 8.5 x 10(-4) mol L-1 and 8.0 x 10(-6) to 5.5 x 10(-3) mol L-1, respectively. The proposed method was applied for the detection of UA and AA in human urine with satisfactory result. (C) 2008 Elsevier Ltd. All rights reserved.
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