期刊
ELECTROCHIMICA ACTA
卷 54, 期 2, 页码 254-260出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2008.08.020
关键词
Ionic liquids; Conductivity; Transport properties; Corrosion
资金
- ARC Centre for Electromaterials Science
- ARC Discovery Fund
- Cytec Canada Inc
Phosphonium cation based ionic liquids (ILs) have become of interest due to their unique chemical and electrochemical stability as well as their promising tribological properties. At the same time. interest has also grown in the use of phosphate and phosphinate based ionic liquids for corrosion protection of reactive metals. In this work we describe the synthesis and characterization of six novel ionic liquids based on the tetraalkylphosponium cation coupled with organophosphate and organophosphinate anions and their sulfur analogues. The conductivity and viscosity of these ILs has been measured and discussed in terms of the nature of the interactions. effect of anion basicity and the extent of ionic character. The reaction of the IL with a ZE41 magnesium aerospace alloy surface is also demonstrated. (c) 2008 Elsevier Ltd. All rights reserved.
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