期刊
ELECTROCHIMICA ACTA
卷 53, 期 17, 页码 5569-5578出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2008.02.086
关键词
Li-ion battery; ionic transport; organic electrolytes; Nernst-Plank equations; electro-neutrality
The ionic conductivity of the organic electrolyte in Li-ion batteries has been modelled. The classical one-dimensional Nernst-Planck approach results in a system of two non-linear parabolic second-order partial differential equations. It is shown that under electro-neutrality conditions this complex system of equations can be reduced to simple diffusion equations with modified diffusion coefficient, facilitating the efficient use of numerical methods. As a result, detailed information about transient and steady-state behaviour of the electrolyte is revealed, including potential gradients and the diffusion and migration fluxes for both Li+ and PF6- ions. Furthermore, an extension of the basic model is presented, taking into account salt dissociation in the electrolyte. The most characteristics of ionic transportation are illustrated with realistic examples of constant-current (dis)charging Li-ion batteries. Some of the numerical simulations are compared with recently reported experimental results. (C) 2008 Elsevier Ltd. All rights reserved.
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