期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 34, 期 -, 页码 105-108出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2013.05.018
关键词
Carbon nanotubes; Peroxidase; Glucose oxidase; Biofuel cells; Hydrogen peroxide
资金
- ANR [Emergence-2010 EMMA-043-02]
- ANR Investissements d'avenir-Nanobiotechnologies [10-IANN-0-02]
- Region Rhones-Alpes
We report the first example of a glucose/H2O2 biofuel cell operating at 5 mM glucose under air at 37 degrees C in 0.14 M NaCl. At a bienzymatic cathode, the direct wiring of horseradish peroxidase (HRP) achieves the electrocatalytic reduction of H2O2 concomitantly produced during the oxidation of glucose by glucose oxidase (GOx) in the presence of O-2. At the bienzymatic anode, the indirect wiring of glucose oxidase achieves electrocatalytic glucose oxidation while catalase removes trace of H2O2 and, in combination with GOx, traces of O-2. The bienzymatic catalysis involved GOx at both electrodes. The biofuel cell exhibits OCV of 450 mV and maximum power output of 30 mu W cm(-2) at 0.3 V in 5 mM glucose and 0.14 M NaCl at 37 degrees C. This represents a novel alternative to the use of copper oxidases in conventional glucose/O-2 biofuel cells for implantableapplications. (C) 2013 Elsevier B.V. All rights reserved.
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