期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 31, 期 -, 页码 116-119出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2013.03.027
关键词
Electrochemiluminescence (ECL); BODIPY; Self assembled monolayer; Optical sensor
资金
- Science Foundation Ireland [10/IN.1/B3021, 10/CE/B1821]
A thin film of the novel surface active ECL luminophore, 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene, BODIPY, is used to demonstrate that the ECL turn on potential can be controlled through the identity of the co-reactant. The films were very stable when in contact with organic solvents and surface coverages of 1-2 nmol cm(-2) are observed. Significantly, the potential at which ECL is generated is dictated by the identity of the co-reactant, either benzoyl peroxide or hydrogen peroxide, which opens new avenues for multi-analyte detection by changing the identity of the co-reactant rather than the dye. (C) 2013 Published by Elsevier BM.
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