期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 12, 期 5, 页码 624-627出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2010.02.015
关键词
Au nanoparticles; Polypyrrole; Composite material; Electrodeposition
资金
- Polish Ministry of Science and Higher Education [NN204 244534]
An easy method of preparation of polymer/metal-nanoparticle composites is reported. KAu(CN)(2) and pyrrole do not react (redox reaction) in solutions of moderate pH. The gold complex, due to its inertness, is stable in the presence of 10 mu M CN- for weeks. Therefore the electrodeposition of controlled amounts of polypyrrole and Au nanoparticles on the graphite surface can be done in one solution by applying a sequence of 0.75 and -1.6 V potentials. Pulse deposition of both components leads to substantial improvement of the layer smoothness and homogenous distribution of Au nanocrystallites. (c) 2010 Published by Elsevier B.V.
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