期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 12, 期 5, 页码 650-652出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2010.02.022
关键词
Electrochemiluminescence; CdS nanocrystals; Ammonia; Heating
资金
- National Natural Science Foundation of China [20705002]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
CdS nanocrystals (NCs) usually exhibit very weak electrochemiluminescence (ECL) emission. It is showed that when CdS NCs were treated by heating in the presence of ammonia (heated-CdS-NH3), greatly enhanced ECL was observed. The ECL of the heated-CdS-NH3 modified glassy carbon electrode (heated-CdS-NH3/GCE) in phosphate buffer solution (pH 7.0) containing 0.1 M K2S2O8 was ca. 310 times higher than that of CdS/GCE. The treatment caused the changes in the morphology and surface electronic structure of CdS NCs, which facilitated the reduction process of CdS, consequently improved the quantity of the excited states (CdS*), leading to enormous enhancement in ECL (c) 2010 Elsevier B.V. All rights reserved.
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