Monoclinic iron hydroxy sulphate: A new route to electrode materials

The monoclinic form of FeOHSO4 was prepared by dehydration of FeSO4 center dot 7H(2)O. We show that reversible insertion of up to similar to-1 Li/f.u. is possible in this compound at an average voltage of 3.2 V. The insertion/deinsertion is a biphasic process. The high voltage plateau, a reversible capacity of 110 mAh/g after 20 cycles and good cycling behavior make this compound an attractive positive electrode material for rechargeable Li-ion batteries, suggesting also that transition metal sulphates need to be explored. (C) 2009 Elsevier B.V. All rights reserved.