An activated carbon with high capacitance from carbonization of a resorcinol-formaldehyde resin

A polymeric activated carbon (PAC) was synthesized from the carbonization of a resorcinol-formaldehyde resin with KOH served as an activation agent. The nitrogen adsorption-desorption at 77 K, X-ray diffraction (XRD) and X-ray photorelectrom spectroscopy (XPS) were used to characterize the prepared PAC. Compared with the commercial activated carbon (Maxsorb: Kansai, Japan), PAC shows superior capacitive performance in terms of specific capacitance, power output and high energy density as electrode materials for supercapacitors. PAC presents a high specific capacitance of 500 F g(-1) in 6 mol l(-1) KOH electrolyte at a current density of 233 mA g(-1) which remained 302 F g(-1) even at a high current density of 4.6 A g(-1). The good electrochemical performance of the PAC was ascribed to well-developed micropores smaller than 1.5 nm, the presence of electrochemically oxygen functional groups and low equivalent series resistance. (C) 2009 Elsevier B.V. All rights reserved.