Study on the effect of Li doping in spinel Li4+xTi5-xO12 (0 ≤ x ≤ 0.2) materials for lithium-ion batteries

The effect of Li doping in spinel Li4+xTi5-xO12 (0 <= x <= 0.2) materials on the structural and electrochemical properties were investigated. The ratio of the capacity in the voltage plateau (1.5 V) to the overall discharge capacity for Li4.1Ti4.9O12 (x = 0.1) and Li4.2Ti4.8O12 (x = 0.2) were higher than that of LiJi5012 especially at high current rates due to their enhanced lithium-ion and electronic conductivity by the substitution of Ti atoms by Li atoms. With the increasing of Li doping amount, lithium-ion and electronic conductivity of Li4+xTi5-xO12 increased, however its cycling stability was depressed when the Li doping was of x = 0.2. The Li doping of x = 0.1, the appropriate Li doping amount, showed improved rate capability and better high rate performance comparing to uncloped Li4+xTi5-xO12 (x = 0). (c) 2008 Elsevier B.V. All rights reserved.