期刊
ELECTROCHEMICAL AND SOLID STATE LETTERS
卷 14, 期 9, 页码 A134-A137出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.3609260
关键词
-
资金
- New Energy and Industrial Technology Department Organization (NEDO)
Li-7 and F-19 double-resonance NMR was applied to examine LiF formed at the surface layer of a LiCoO2 electrode during charge-discharge cycles in an electrochemical cell with organic electrolytes containing LiPF6. Not only the chemical shifts observed by using cross polarization (CP) between Li-7 and F-19, but also the magnetization-transfer curves during CP indicate the observed CP signals are of LiF in the LiCoO2 electrode. Examination of the effect of Li-7-Li-7 spin diffusion between LiF and LiCoO2 on the Li-7 spin-lattice relaxation time suggested that LiF forms macroscopic domains which is not directly adhere the LiCoO2 particles. (C) 2011 The Electrochemical Society. [DOI: 10.1149/1.3609260] All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据