期刊
ELECTROCHEMICAL AND SOLID STATE LETTERS
卷 13, 期 4, 页码 A43-A47出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.3298353
关键词
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资金
- NSERC (Canada)
We have synthesized LiFePO4F by a simple solid-state route as a pure single phase, which we show is isostructural with that of the minerals tavorite and amblygonite, and we report the first isolation of its fully lithium-inserted crystalline analog, Li2FePO4F. We show that the latter adopts a triclinic P (1) over bar tavorite-type framework that is very closely related to the parent phase. The redox activity between these two compositions is very facile and occurs with an 8% change in volume to result in a reversible and stable capacity of about 145 mAh/g. The electrochemical cycling at both room temperature and 55 degrees C is very stable. (C) 2010 The Electrochemical Society. [DOI: 10.1149/1.3298353] All rights reserved.
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