期刊
ELECTROCHEMICAL AND SOLID STATE LETTERS
卷 12, 期 4, 页码 F5-F7出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.3072775
关键词
ionic conductivity; phosphorus compounds; solid electrolytes; tantalum compounds; zirconium compounds
资金
- Industrial Technology Research [05A18011d]
- New Energy and Industrial Technology Development Organization (NEDO) of Japan
Highly tetravalent zirconium-ion-conducting solid electrolytes, Zr1+x/4TaP3-xSixO12, were developed by partially substituting the P5+ ions in the Nasicon-type ZrTa(PO4)(3) solid, with Si4+ ions having larger ionic size and lower valence. Among the samples prepared, Zr41/40TaP2.9Si0.1O12 (x=0.1) exhibited the highest Zr4+ ion conductivity of 3.04x10(-4) S cm(-1) at 600 degrees C.
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