期刊
ELECTROCHEMICAL AND SOLID STATE LETTERS
卷 11, 期 12, 页码 F27-F29出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.2978963
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资金
- Academy of Sciences of the Czech Republic [KAN100400702]
Single-phase iron-substituted nanocrystalline ruthenium dioxide with composition Ru(0.98)Fe(0.02)O(2-y) and Ru(0.70)Fe(0.30)O(2-y) of rutile structure was prepared. The electrocatalytic behavior of the prepared materials was tested with respect to oxygen evolution reaction and chlorine evolution reaction (CER) The substitution with iron leads to a slight increase of the material's activity toward oxygen evolution. The selectivity of iron-doped materials in parallel oxygen and chlorine evolution is affected by oxygen content in the electrolyte solution. The CER is preferred in oxygen-free solutions; in oxygen-saturated solutions oxygen evolution is enhanced. (C) 2008 The Electrochemical Society. [DOI: 10.1149/1.2978963] All rights reserved.
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