期刊
ELECTROANALYSIS
卷 27, 期 1, 页码 156-165出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201400412
关键词
2,4,6-Tribromophenol; Alcohols; Electrooxidation; Gas chromatography; Mass spectrometry
资金
- Operational Program Research and Development for Innovations - European Regional Development Fund [CZ.1.05/2.1.00/03.0058]
- Operational Program Education for Competitiveness - European Social Fund [CZ.1.07/2.3.00/30.0041]
- Palacky University in Olomouc [IGA_PrF_2014031]
- Grant Agency of the Czech Republic [P206/12/1150]
Electrooxidation of 2,4,6-tribromophenol on platinum gauze electrode in 90% (v/v) alcohol (methanol, ethanol, propan-1-ol, butan-1-ol) was studied. Products were investigated by gas chromatography/mass spectrometry. Structures of several different types of monomeric as well as dimeric alkoxy derivatives have been suggested according to mass spectra of the detected products. Series of 2,6-dibromo-4-alkoxyphenols, 2,4,6-tribromo-6-alkoxycyclohexa-2,4-dien-1-ones and 2,6-dibromo-6-alkoxycyclohex-2-ene-1,4-diones were found. By analogy to identified monomeric alkoxy derivatives, a serie of dimeric 2,6-dibromo-4-(2,6-dibromo-4-alkoxyphenoxy)phenols was suggested and identified in respective chromatograms as well.
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