期刊
ELECTROANALYSIS
卷 25, 期 9, 页码 2159-2165出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201300220
关键词
Ordered mesoporous carbon composite; Direct electrochemistry; Horseradish peroxidase
资金
- Shanghai Natural Science Foundation [13ZR1418300]
- National Natural Science Foundation of China [21275054]
A novel magnetic ordered mesoporous carbon composite was prepared. Electrochemical measurements showed that the ordered mesoporous carbon composite provided an excellent matrix for the co-adsorption of horseradish peroxidase (HRP). HRP could be separated and collected by the application of a magnetic field and its direct electron-transfer could be achieved in the solution, not on the electrode thereby preventing the degradation of the enzyme. The cyclic voltammetric experimental results of HRP indicated that HRP displayed a pair of stable peaks with a formal potential of -0.306V in PBS. The resulting biosensor exhibited fast amperometric response to hydrogen peroxide.
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