期刊
ELECTROANALYSIS
卷 24, 期 12, 页码 2249-2256出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/elan.201200440
关键词
Electronic tongue; Sensor array; Heavy metals; Ion selective electrode; Soil
资金
- Spanish Ministry of Science and Innovation, MCINN (Madrid) [CTQ2010-17099]
- Program ICREA Academia
- Universitat Autonoma de Barcelona
A sensor array of 9 potentiometric PVC sensors has been employed for the simultaneous determination of heavy metals in soil. Sensors were firstly characterized in their response: Nernstian behavior, a concentration range from ca. 10-6 to 10-2 M and selectivity coefficients confirming that all sensors had cross-response for the target ions. The mixed response system was modeled employing Artificial Neural Networks. The proposed tool was applied to the determination of Pb2+, Cd2+, Cu2+ and Zn2+ in soils at the mg kg-1 level with satisfactory performance. Results were compared and validated against AAS reference methodology, with correlations R2>0.948 for the four heavy metals considered.
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