期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 6, 期 11, 页码 2121-2126出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.5b00750
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资金
- New Energy and Industrial Technology Development Organization (NEDO) of Japan
We have made the first success in the same-view imagings of 2D nano-XAFS and TEM/STEM-EDS under a humid N-2 atmosphere for Pt/C cathode catalyst layers in membrane electrode assemblies (MEAs) of polymer electrolyte fuel cells (PEFCs) with Nafion membrane to examine the degradation of Pt/C cathodes by anode gas exchange cycles (start-up/shut-down simulations of PEFC vehicles). The same-view imaging under the humid N2 atmosphere provided unprecedented spatial information on the distribution of Pt nanoparticles and oxidation states in the Pt/C cathode catalyst layer as well as Nafion ionomer-filled nanoholes of carbon support in the wet MEA, which evidence the origin of the formation of Pt oxidation species and isolated Pt nanoparticles in the nanohole areas of the cathode layer with different Pt/ionomer ratios, relevant to the degradation of PEFC catalysts.
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