4.8 Article

Interfacial Charge Transfer Anisotropy in Polycrystalline Lead Iodide Perovskite Films

期刊

JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 6, 期 8, 页码 1396-1402

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.5b00431

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资金

  1. NTU NAP [M4080511]
  2. Singapore Ministry of Education [MOE2013-T2-1-044]
  3. Singapore-Berkeley Research Initiative for Sustainable Energy (SinBeRISE) Create Programme

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Solar cells based on organic-inorganic lead iodide perovskite (CH3NH3PbI3) exhibit remarkably high power conversion efficiency (PCE). One of the key issues in solution-processed films is that often the polycrystalline domain orientation is not well-defined, which makes it difficult to predict energy alignment and charge transfer efficiency. Here we combine ab initio calculations and photoelectron spectroscopy to unravel the electronic structure and charge redistribution at the interface between different surfaces of CH3NH3PbI3 and typical organic hole acceptor Spiro-OMeTAD and electron acceptor PCBM. We find that both hole and electron interfacial transfer depend strongly on the CH3NH3PbI3 surface orientation: while the (001) and (110) surfaces tend to favor hole injection to Spiro-OMeTAD, the (100) surface facilitates electron transfer to PCBM due to surface delocalized charges and hole/electron accumulation at the CH3NH3PbI3/organic interfaces. Molecular dynamic simulations indicate that this is due to strong orbital interactions under thermal fluctuations at room temperature, suggesting the possibility to further improve charge separation and extraction in perovskite-based solar cells by controlling perovskite film crystallization and surface orientation.

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