期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 6, 期 18, 页码 3645-3649出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.5b01756
关键词
-
类别
资金
- National Science Foundation [DMR-1105185, CHE-1266154]
- Lilly Endowment, Inc.
- Indiana METACyt Initiative
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1266154] Funding Source: National Science Foundation
Graphene fluorination with XeF2 is an attractive method to introduce a nonzero bandgap to graphene under mild conditions for potential electro-optical applications. Herein, we use well-defined graphene nanostructures as a model system to study the reaction mechanism of graphene fluorination by XeF2. Our combined experimental and theoretical studies show that the reaction can proceed through a radical cation mechanism, leading to fluorination and sp(3)-hybridized carbon in the basal plane.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据