Adsorption of Nitrogen-Containing Compounds from Model Fuel over Sulfonated Metal-Organic Framework: Contribution of Hydrogen-Bonding and Acid-Base Interactions in Adsorption

Adsorptive denitrogenation (ADN) was carried out by adsorption of indole (IND) and quinoline (QUI) over metal-organic frameworks (MOFs) including acidic UiO-66-SO3H for the first time. The adsorbed amount of IND increased with increasing content of -SO3H in UiO-66. The favorable effect of the -SO3H group on the adsorptive removal of IND could be explained by hydrogen bonding between the O of -SO3H and the H of IND, which was firmly supported by the adsorption of pyrrole and methylpyrrole and by theoretical calculations. The application of an -SO3H group in the adsorptive removal of neutral IND is meaningful since neutral nitrogen-containing compounds are not easy to remove and since UiO-66-SO3H is reusable after simple washing with ethanol. The expected increase in QUI adsorption (due to acid-base interaction) with acidic -SO3H was observed when QUI was present at low concentrations (