期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 119, 期 42, 页码 23928-23942出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.5b06219
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The structure of oxidic precursors of supported NiMo hydrodesulfurization catalysts has been investigated in-depth by the combination of laser Raman spectroscopy and X-ray absorption spectroscopy measured at the Mo and Ni K edges at the different stages of the preparation. The oxidic catalysts were prepared by incipient wetness impregnation of delta-alumina with a solution obtained by dissolving MoO3 in H2O2 and subsequently adding Ni(NO3)(2)center dot 6H(2)O in this as-prepared solution (8 wt % MoO3; 2 wt % NiO). The formation of the 6-molybdoaluminate Anderson-type heteropolyanion (AlMo6O24H6)(3-) and of a mixture of oxohydroxo nickel species and bulk and/or surface NiAl-layered double hydroxide dispersed at the surface of the support has been identified after drying. Upon further thermal treatment at 723 K under dried air, calcined dehydrated catalyst is constituted of highly distorted isolated or partially condensed tetrahedral Mo units with terminal mono-oxo groups and of bulk and/or surface NiAl2O4-type and NiO-type species. After further exposure of the calcined catalyst to air moisture, a partial recovery of the Anderson-type molybdenum heteropolyanion and NiAl-layered double hydroxide species is evidenced by X-ray absorption spectroscopy. The nature and dispersion of active species formed after sulfidation under H2S/H-2 of the different oxidic catalysts (dried-NiMo, dehydrated-calcined NiMo, and calcined-NiMo samples) are finally discussed in light of the structure of the parent oxidic precursors.
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