A 35 Myr North American leaf-wax compound-specific carbon and hydrogen isotope record: Implications for C4 grasslands and hydrologic cycle dynamics

Hydrology, source region, and timing of precipitation are important controls on the climate of the Great Plains of North America and the composition of terrestrial ecosystems. Moisture delivered to the Great Plains varies seasonally and predominately derives from the Gulf of Mexico/Atlantic Ocean with minor contributions from the Pacific Ocean and Arctic region. For this work, we evaluate long-term relationships for the past similar to 35 million years between North American hydrology, climate, and floral change, using isotopic records and average carbon chain lengths of higher plant n-alkanes from Gulf of Mexico sediments (DSDP Site 94). We find that carbon isotope values (delta C-13) of n-alkanes, corrected for variations in the delta C-13 value of atmospheric CO2 provide minor evidence for contributions of C-4 plants prior to the Middle Miocene. A sharp spike in C-4 input is identified during the Middle Miocene Climatic Optimum, and the influence of C-4 plants steadily increased during the Late Miocene into the Pleistocene - consistent with other North American records. Chain-length distributions of n-alkanes, indicative of the composition of higher plant communities, remained remarkably constant from 33 to 4 Ma. However, a trend toward longer chain lengths occurred during the past 4 million years, concurrent with an increase in delta C-13 values, indicating increased C-4 plant influence and potentially aridity. The hydrogen isotope values (delta D) of n-alkanes are relatively invariant between 33 and 9 Ma, and then become substantially more negative (75 parts per thousand) from 9 to 2 Ma. Changes in the plant community and temperature of precipitation can solely account for the observed variations in delta D from 33 to 5 Ma, but cannot account for Plio-Pleistocene delta D variations and imply substantial changes in the source region of precipitation and seasonality of moisture delivery. We posit that hydrological changes were linked to tectonic and oceanographic processes including the shoaling and closure of the Panamanian Seaway, amplification of North Atlantic Deep Water Production and an associated increase of meridional winds. The southerly movement of the Intertropical Convergence Zone near 4 Ma allowed for the development of a near-modern pressure/storm track system, driving increased aridity and changes in seasonality within the North American interior. (C) 2010 Elsevier B.V. All rights reserved.