Mercury isotopic composition of hydrothermal systems in the Yellowstone Plateau volcanic field and Guaymas Basin sea-floor rift

To characterize mercury (Hg) isotopes and isotopic fractionation in hydrothermal systems we analyzed fluid and precipitate samples from hot springs in the Yellowstone Plateau volcanic field and vent chimney samples from the Guaymas Basin sea-floor rift. These samples provide an initial indication of the variability in Hg isotopic composition among marine and continental hydrothermal systems that are controlled predominantly by mantle-derived magmas. Fluid samples from Ojo Caliente hot spring in Yellowstone range in 6202 Hg from -1.02%. to 0.58%o (+/- 0.11%, 2SD) and solid precipitate samples from Guaymas Basin range in delta Hg-202 from -0.37%. to -0.01% (+/- 0.14%, 2SD). Fluid samples from Ojo Caliente display mass-dependent fractionation (MDF) of Hg from the vent (delta Hg-202=0.10% +/- 0.11%, 2SD) to the end of the outflow channel (delta Hg-202=0.58% +/- 0.11%, 2SD) in conjunction with a decrease in Hg concentration from 46.6 pg/g to 20.0 pg/g. Although a small amount of Hg is lost from the fluids due to co-precipitation with siliceous sinter, we infer that the majority of the observed MDF and Hg loss from waters in Ojo Caliente is due to volatilization of Hg-(aq)(0) to Hg-(g)(0) and the preferential loss of Hg with a lower delta Hg-202 value to the atmosphere. A small amount of mass-independent fractionation (MIF) was observed in all samples from Ojo Caliente (Delta Hg-199=0.13%+/- 10.06%, 2SD) but no significant MIF was measured in the sea-floor rift samples from Guaymas Basin. This study demonstrates that several different hydrothermal processes fractionate Hg isotopes and that Hg isotopes may be used to better understand these processes. (C) 2008 Elsevier B.V. All rights reserved.