U-Th dating of carbonate nodules from methane seeps off Joetsu, Eastern Margin of Japan Sea

We performed U-Th radioactive disequilibrium analyses of carbonate nodules and sediment samples recovered from methane seep sites off Joetsu, of the eastern margin of Japan Sea, to decipher the active period of the methane seep. The carbonates contain Th-230, part of which is located in detritus such as silicate and organics, at the time of precipitation. The initial Th-230 renders accurate dating with U-Th radioactive disequilibrium method difficult. We assessed the feasibility of correction using radioactive disequilibrium data of ambient sediment to overcome this difficulty. A (Th-230/Th-232)-( U-214/Th-232) isochron drawn by three chips divided from a carbonate nodule (PC05-04-50) passed through data points of local sediments. We conclude that the problem of initial 230Th can be resolved by measurements of local sediments. Results show that carbonate nodules include local sediment as impurities. Furthermore, the results of trace element analyses such as Rb, Zr, Nb, REE, Pb, and Th also support the idea. In all, 18 carbonate samples were dated with correction of initial Th-230 using the mean value of local sediment in this study. The U-Th correction ages show 12-35ka with an isochron age of 26 +/- 3ka. Results indicate that during the time interval of U-Th ages, from 12ka to 35ka, environmental conditions must have been favorable for enhanced methane flux through sediment. The extensive methane flow period at 20ka accords with the lowest-stand sea level during the last glacial age. Results of this study also suggest that U-Th ages of carbonate are useful as a reliable chronometer with regard to methane seep activation. In order to acquire U-Th ages of carbonate at methane seep sites, however, it is important to evaluate the amount of initial Th-230 accurately using the value of sediment. (C) 2008 Elsevier B.V. All rights reserved.