4.5 Article

Hyperpolarized para-Ethanol

期刊

JOURNAL OF PHYSICAL CHEMISTRY B
卷 119, 期 10, 页码 4048-4052

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AMER CHEMICAL SOC
DOI: 10.1021/jp512128c

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  1. Swiss National Science Foundation (SNSF)
  2. Swiss Commission pour la Technologie et l'Innovation (CTI)
  3. Ecole polytechnique federale de Lausanne (EPFL)
  4. French Centre national de la recherche scientifique (CNRS)
  5. European Research Council (ERC)

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We show that an imbalance between the populations of singlet (S) and triplet (T) states in pairs of magnetically equivalent spins can be generated by dissolution dynamic nudear polarization: In partly deuterated ethanol ((CD3CH2OD)-C-13), this T/S imbalance can be transferred by cross-relaxation to observable, enhanced signals of protons and coupled C-13.

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