期刊
DYES AND PIGMENTS
卷 100, 期 -, 页码 241-246出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2013.09.018
关键词
Phosphorescence chemosensor; Anion recognition; Dihydrogen phosphate sensing; Chiral recognition; Iridium complex; Amino acid sensing
资金
- National Research Foundation of Korea(NRF)
- Korea govemment(MEST) [2012-0002571]
- Korea govemment(MEST), National Creative Research Initiative [2012R1A3A2048814]
As a versatile platform for phosphorescent chemosensors, bis(benzylic amine) derivative 6 was synthesized. Two urea groups could be readily introduced for phosphorescent chemosensor 1. A preorganized binding pocket could induce a selective phosphorescence enhancement with H2PO4-. A new iridium complex 2 bearing two thiourea groups as well as glucopyranosyl chiral barriers is reported as a first chiral phosphorescent chemosensor for amino acids. (C) 2013 Elsevier Ltd. All rights reserved.
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