期刊
DYES AND PIGMENTS
卷 103, 期 -, 页码 161-167出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2013.11.016
关键词
Piezochromic fluorescence; Solvatochromism; Tri-arm; Bathochromic shift; Planarization; Triphenylamino-quinoline
资金
- National Science Council, Taiwan, R.O.C. [102-2221-E-110-084-MY3, 102-2221-E-110-080]
Two tri-armed piezochromic fluorescent molecules of tris(4-(4-phenylquinolin-2-yl)phenyl)amine (TPA-3Qu) and tris(4-(6-(9H-carbazol-9-yl)-4-phenylquinolin-2-yl)phenyl)amine (TPA-3QuCz) were prepared and found to exhibit keen fluorescence responses toward compression. With the framework of a twisted, pyramidal triphenylamine (TPA) center connecting to three large quinolinecarbazole (QuCz) arms, the amorphous TPA-3QuCz exhibited a large bathochromic shift of 112 nm under gentle grinding forces, which is different from the small shift of 32 nm for TPA-3Qu under applying a relatively-large pressure of 10 MPa. Conformational transformations involving planarization of the arms were proposed to account for the observed fluorescence responses of TPA-3QuCz and TPA-3Qu towards pressure. (C) 2013 Elsevier Ltd. All rights reserved.
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