期刊
DYES AND PIGMENTS
卷 96, 期 2, 页码 364-371出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2012.08.014
关键词
Thiourea; Naphthoquinone; Anthroquinone; Fluoride; H-bonding; Charge transfer
Two new colorimetric sensors for fluoride ions [N,N'-(anthracene-9,10-dione-1,2-diyldicarbamothioyl) dibenzamide] and [N,N'-(naphthalene-1,4-dione-2,3-diyldicarbamothioyl) dibenzamide] have been prepared and characterized using various spectral techniques. The quinonoid receptors exhibited high selectivity for fluoride ion detection over other anions. The association constant of the receptor-F complexes were found to be 6.3 x 10(8) and 7.7 x 10(15) M-1 for the anthroquinone and naphthoquionone receptors, respectively. H-1 NMR studies indicated that the fluoride ion sensing by the receptors is due to the formation of H-bonds between F-ions and the -NH moiety of the receptors which has been enhanced by directly attaching signaling unit to the receptor unit in the naphthoquinone derivative. The naphthoquinone receptor also exhibited colorimetric sensing of fluoride ions present in commercially available toothpaste samples in aqueous medium. The structural and electronics properties of the sensors and their fluoride complexes were also investigated using ab initio DFT calculations. (C) 2012 Elsevier Ltd. All rights reserved.
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