期刊
DYES AND PIGMENTS
卷 97, 期 3, 页码 397-404出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2013.01.014
关键词
DSSC; Bi-anchoring molecules; Carbazole; Diphenylamine; Planarity; Impedance
资金
- DST, New Delhi [SR/S1/PC-49/2009]
- India-Spain Joint Collaborative project [DST/INT/Spain/P-37/11]
Two bianchored metal free organic dyes (Car-th-CN and Dpa-th-CN) were designed and synthesized for DSSC application, in which carbazole or diphenylamine moieties were used as the donor, cyano vinyl thiophene unit as the pi-bridge and cyanoacrylic acid group as the electron acceptor. The structures of the synthesized dyes were confirmed by NMR, HR-Mass and elemental analysis. The optical, electrochemical, theoretical and photovoltaic properties of the synthesized dyes were investigated. Fabricated photovoltaic devices based on carbazole unit as a donor (Car-th-CN) showed a maximum current conversion efficiency of 4.04% under AM 1.5 illumination (85 mW cm(-2)) and monochromatic incident photon to current efficiency (IPCE) of 38.1%. The reason for the higher efficiency of Car-th-CN is due to the planar nature of carbazole moiety and hence increases the capability of adsorbed dye amount and electron lifetime in TiO2 surface. (c) 2013 Elsevier Ltd. All rights reserved.
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