期刊
DYES AND PIGMENTS
卷 96, 期 1, 页码 189-195出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2012.07.007
关键词
Cyanine dye; Third-order; Nonlinear optical material; Z-Scan; Functional dyes; Optical material
资金
- National Natural Science Foundation of China [51273136, 20902065, 21071105]
- National High Technology Research and Development Program of China (863 Program) [SQ2009AA06XK1482331]
- Natural Science Fund, Jiangsu Province [BK2009113]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
A series of unsymmetric pentamethine cyanine dyes featuring benzoxazolyl and benzothiazolyl groups were synthesized, the structures were characterized by H-1 NMR, UV-vis absorption spectroscopy and mass spectrometry. The dyes with different anions such as chloride, tetraphenylborate and tetra(4-fluorophenyl)borate were also obtained and their solubility can be changed by the choice of the anion part. The third-order nonlinear optical properties were measured by the Z-scan technique with a pico-second laser beam at 532 nm in DMF solution. The third-order nonlinear optical susceptibilities chi((3)) and the second-order hyperpolarizabilities gamma' were obtained. The results reveal that these dyes exhibit strong reverse saturable absorption and nonlinear refraction. (C) 2012 Elsevier Ltd. All rights reserved.
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