期刊
DYES AND PIGMENTS
卷 98, 期 3, 页码 486-492出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2013.03.017
关键词
Cyanostilbene derivatives; Isomers; Mechanochromic; Thermochromic; Crystal structure; Phase transition
资金
- National Basic Research Program of China [2010CB635108, 2011CBA00700]
- International S&T Cooperation Program, China [2012DFA-51210]
Two isomers (TPA-CNa and TPA-CNb) consisting of twisted triphenylamine and cyanostilbene were synthetized by Knoevenagel condensation and C-N coupling reaction. The fluorescent colours of two isomers in crystalline state were sky-blue for TPA-CNa and green for TPA-CNb with quantum yields (Phi(f)) of 44.9% and 7.7%, respectively. The single crystal X-ray diffractometry revealed the fully different molecular conformations and packing modes of TPA-CNa (planar) and TPA-CNb (twisting), which might be the reason for different Phi(f). The reversible mechanochromic and thermochromic fluorescence switching was observed in crystalline TPA-CNa powders. The sky-blue crystals were changed into the green-emissive solids after grinding, and they recovered their original state upon heating at 60 degrees C over 2 min. The reversible conversion of fluorescence colour was also realized by a pure thermal process. Powder X-ray diffractometry clearly demonstrated that the mechanochromic and thermochromic behaviour could be attributed to the crystal-to-amorphisation phase transition. (C) 2013 Elsevier Ltd. All rights reserved.
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