期刊
DYES AND PIGMENTS
卷 88, 期 2, 页码 149-155出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2010.05.015
关键词
Methylene blue; Methylene violet; CI Basic Blue 9; Thiazine; Hydrolysis; DFT
资金
- Engineering and Physical Sciences Research Council [EP/E036244/1] Funding Source: researchfish
- EPSRC [EP/E036244/1] Funding Source: UKRI
A detailed study of the action of alkali on methylene blue (Cl. Basic Blue 9) and other thiazine dyes was carried out through a combination of UV/visible spectroscopy, thin layer chromatography, mass and NMR spectrometry and computational methods. In 0.1 M aq alkali solution, methylene blue forms a highly coloured, lipophilic species that is mainly Bernthsen's methylene violet i.e. a hydrolysis decomposition product, this being contrary to the report of a red N-hydroxy methylene blue adduct. The nature of the heterocyclic nitrogen atom in C.I. Basic Blue 9 is discussed and it is concluded there is no basis for the proposal of nucleophile addition at this site of the dye. In contrast, other thiazine dyes are deprotonated by alkali to form their neutral, highly coloured, lipophilic conjugate base forms. (C) 2010 Elsevier Ltd. All rights reserved.
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