期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 310, 期 -, 页码 66-105出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2015.04.011
关键词
Titania; Photocatalysis; Slurries; Dispersions; Mechanisms; Kinetics; Models
资金
- EPSRC [EP/J500148/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/J500148/1] Funding Source: researchfish
A brief, historical overview of 10 apparently different, although in some cases, upon inspection, closely related, popular proposed reaction mechanisms and their associated rate equations, is given and in which the rate expression for each mechanism is derived from basic principles, Appendix A. In Appendix B, each of the 5 main mechanisms are tested using datasets, comprising initial reaction rate vs. organic pollutant concentration, [P] and incident irradiance, rho, data, reported previously for TiO2, where P is phenol, 4-chlorophenol and formic acid. The best of those tested, in terms of overall fit, simplicity, usefulness and versatility is the disrupted adsorption kinetic model proposed by Ollis. The usual basic assumptions made in constructing these mechanisms are reported and the main underlying concerns explored. (C) 2015 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据