期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 797, 期 -, 页码 1-7出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2015.07.038
关键词
Ferrocene derivatives; X-ray crystal structure; Copper compounds; Triazolium salts
资金
- Ministere de l'Enseignement Superieur et de la Recherche
- Universite du Maine
The first synthesis of a triazolium salt with ferrocene-based planar chirality is described. It was obtained from enantiopure Kagan's acetal, via the construction of a lactam intermediate. The corresponding 1,2,4-triazolylidene-Cu(I) complex was prepared. Its structure as well as the parent triazolium salt were characterized by X-ray diffraction analysis. (C) 2015 Elsevier B.V. All rights reserved.
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