期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 780, 期 -, 页码 43-48出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2014.12.040
关键词
Ruthenium; Olefin metathesis; N-Heterocyclic carbene; Density functional theory
资金
- European Research Council [227817]
- EU [CP-FP 211468]
- Engineering and Physical Sciences Research Council
- Royal Society
- Spanish MINECO [RYC-2009-05226]
- European Commission [CIG09-GA-2011-293900]
- EPSRC [EP/K039210/1, EP/K031252/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K031252/1, EP/K039210/1] Funding Source: researchfish
- European Research Council (ERC) [227817] Funding Source: European Research Council (ERC)
The commercially-available metathesis pre-catalyst M-23 has been evaluated alongside new complex [RuCl2((3-phenyl)indenylidene)(PPh3)(SIPrOMe)] (1), which bears a para-methoxy-substituted N-heterocyclic carbene ligand. Several model metathesis reactions could be conducted using only parts-permillion levels of ruthenium catalyst. The effects of the different NHC ligands on reactivity have been explored. (C) 2015 Elsevier B. V. All rights reserved.
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