期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 788, 期 -, 页码 27-32出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2015.04.019
关键词
Nickel complex; Pincer-type ligand; N-heterocyclic carbene; Ni(II)-N-heterocyclic carbene complex; Suzuki reaction
资金
- National Natural Science foundation of China [21321061, 21072134, J1103315/J0104]
Air- and moisture-stable nickel(II) complexes 2a-c of CNC pincer-type N-heterocyclic carbene ligands have been prepared from the corresponding imidazolium salts by carbene-transfer reaction of a silver-NHC complex with Ni(DME)Cl-2 (DME = dimethoxylethane). Pincer complexes 2a-c are characterized by mass and NMR spectroscopy. The structure of 2a is also identified by X-ray diffraction analysis. Pincer complex 2a has been shown to be active catalyst for the Suzuki coupling reactions. (C) 2015 Elsevier B.V. All rights reserved.
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