期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 3, 页码 1946-1951出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo502596k
关键词
-
资金
- National Natural Science Foundation of China [21302200]
An iridium-catalyzed direct C-7 selective C-H alkynylation of indolines at room temperature, for the first time, has been developed via C-H bond activation. Furthermore, the first example of direct C-H alkynylation of carbazoles at the C1 position is also achieved. More importantly, the resulting product can be readily transformed into C7-alkynylated indoles, further widening the C-7 derivatization of indoles and highlighting the synthetic utility of this methodology.
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