期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 24, 页码 11948-11952出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b01701
关键词
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资金
- National Science Foundation [1300878]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1300878] Funding Source: National Science Foundation
The intramolecular reactions of olefinic N-heterocycles have been studied. In triflic acid-promoted reactions, conjugate addition is observed with pyrazine-, 2-pyrimidine-, and 2-quinoxaline-based olefins and a phenyl group nucleophile. Markovnikov addition is observed with pyridine and 5-quinoxaline-based olefins. These results are in accordance with previous observations relating the type of addition-conjugate or Markovnikov-to the positions of olefinic substituents of the N-heterocycle.
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