期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 80, 期 21, 页码 11123-11130出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b01793
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资金
- National Natural Science Foundation of China [21572272, 21502232]
- Natural Science Foundation of Jiangsu Province [BK20140655]
- Foundation of State Key Laboratory of Natural Medicines [ZZJQ201306]
A formal 1,6-conjugated addition-mediated [2+1] annulation to synthesize spiro[2.5]octa-4,7-dien-6-one with p-quinone methides and sulfur ylides has been described. This domino-type process was highly diastereoselective and exhibited good functional group tolerance and scalability without the use of metals and bases.
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